An Easy Access to Spiroannulated Glyco-Oxetane, -thietane and -azetane Rings: Synthesis of Spironucleosides

Roy, Ashim and Achari, Basudeb and Mandal, Sukhendu B (2006) An Easy Access to Spiroannulated Glyco-Oxetane, -thietane and -azetane Rings: Synthesis of Spironucleosides. Tetrahedron Letters, 47 (23). pp. 3875-3879.

[img]

PDF
Restricted to IICB Scientists only

Download (144Kb) | Request a copy

    Abstract

    The key intermediate 11 derived from D-glucose and possessing bis-mesylmethyl (MsOÆCH2–) functionality at C-4, was used to generate spirocycles 12, 13 and 15 via one-step procedures. The spirocompounds 12 and 13 were subsequently converted into the corresponding spironucleosides 24 and 26 in good yield using Vorbru¨ggen reaction conditions.

    Item Type: Article
    URI: http://www.eprints.iicb.res.in/id/eprint/1110
    Subjects: Chemistry
    Divisions: Indian Institute of Chemical Biology
    Depositing User: Mr Santanu Sadhukhan
    Date Deposited: 29 Dec 2011 11:25
    Last Modified: 03 Feb 2012 14:28
    Official URL: http://dx.doi.org/10.1016/j.tetlet.2006.03.175
    Links:

    Actions (login required)

    View Item